There are three different alloys containing 45% silver.
There is a quaternary alloy with copper, zinc and cadmium. Banned in the EU because of a perceived danger caused by licking or sucking jewellery. But banned all the same.
Another quaternary alloy sees the cadmium replaced with a small %ge of tin
Then there is a ternary alloy where the cadmium is simply removed.
Which one are you using? Check your supplier's data sheet.
Personally (and with no medical qualifications whatsoever) I believe that you would come to no harm no matter which one you used.
Of more concern is the ugly and appalling colour match of these alloys on copper. Make it less obvious by the application of a heavy hammer to the thumb 👍
Or use a glue.
Then spray the bracelet with copper paint
Keith