I am no expert, just an amateur at all forms of welding, so for what it is worth here is what I have learned in a year or so of playing around…
1 Cleanliness is everything. Especially with aluminium. Stainless is not so hard since it tends to be cleaner. Clean the filler rod too.
2 Remember to turn the gas on! Seems obvious enough but I have forgotten at least twice. If you do forget, clean the job again. (Use the right gas too, not the mixture intended for MIG. I haven't done that, but I gather it is not a good idea.)
3 If you touch the tungsten on the job, stop. Regrind the tungsten and clean the job again. It will not get any better if you try to keep on going.
4 If you are making stainless tanks, like I was on my first major job, do not flange the joints. A nicely fitted butting corner is much easier to weld and often does not even need filler.
5 Aluminium is harder to TIG, get some practice before trying anything critical with it. If it starts to get out of hand, stop and let it cool for a bit. Some of my best joints have that "stack of dimes" look, many don't!
6 Buy a reasonably capable machine, Having HF start in particular is good, scratch start is for experts, not learners. Arc force is good on MMA, but not needed for TIG. All those settings might look a bit daunting, but better to have them and not need them than vice versa.
I mostly don't use TIG for welding mild steel, I use the same machine but on the DC stick setting. I find that the welds I can do that way are so much nicer than what I used to get with an old AC arc machine that it is not worth expending the argon to try to do better with TIG.
I have a foot pedal, but I am not multidextrous enough to get much value out of it yet. The machine also does pulse, but I haven't made a lot of use of that yet either. I have welded stainless, aluminium , and copper, the latter being inch size plumbing tubing, quite thin in the wall. It didn't come out very tidy but it holds vacuum in OK.
Welding is a trade in its own right, as an amateur I do not expect to ever get to the level of the professionals, but with practice it is possible to do a reasonable job .
John