UN standards are:
UNC – coarse
UNF – fine
UNEF – extra fine
UNS – special (pitches not covered by the other categories)
UNR – must have root radius
1/4 – 32 is specified in the UNEF category. I don't know why it would be described as UNS.
Thread classes are 1A/2A/3A and 1B/2B/3B the number being the fit (1=loose to 3=close). A is used for external threads; B for internal