Unless you have the paperwork to confirm that the boiler has been tested and certified, keep the pressures low.
If pressure vessel, under air pressure fails, it can be as dangerous, or even more so than a boiler under pressure.
Ask my friend who is minus his finger ends! (A compressed air tank exploded when he was beside it. )
You could try feeding compressed air into the Regulator, (disconnect from the feed from the boiler! ) and see what happens.
If nothing investigation for jammed / seized cylinder or motion or blocked pipes would be in order.
This assumes that the valve settings are correct.
If all else fails, you need to start checking that all passages are open, starting with the ports into the cylinder (means removing the cylinder ends ) and working back, through the valves and pipework, regulator, until you reach the boiler take off.
It is not unknown for the passage from port to cylinder not to be drilled through!
Even Fred Dibnah had to open up the passages on his engine whilst on his final round Britain trip!
Howard