Hi Alan,
Carbon deposits – from brazing?
Where did they come from? Not the gas, nor silver solder nor the copper.
Or is it that the flux esidues are black? In this case neither citric acid nor sulphuric will help. A more likely explaination is that the flux has been heated too long or to too high a temperature and degraded.
Use a stiff wire brush or other mechanical means to clean things up. Inspect and test the joints.
Stop it happening again by using a longer life flux like HT5
Regards
Keith