I appreciate the frustration – I spotted that mine was very slightly off after facemilling (2.5"
what was about a 3" square piece of 1/4" plate. It had the very smallest 'dish' in it which was only visible on blueing it onto a surface plate, which I realised meant the mill head wasn't 100.00% square to the table. It was a thou and this means about 0.046 degrees error in my case.
Needless to say, spent a lot of time fiddling with it – probably striving for unnecessary accuracy – and as the OP and others note, after all maner of careful setting (mine has a dowel pin for location) it still 'slipped' on being tightened up.
What i ended up doing was nipping it then carefully use a dead blow rubber mallet to get it spot on as i progressively tightedn it all up. Else no matter how careful I was, it 'slipped' ever so slightly if I just did it up in one go from the point it was supposed to be square.
Personally, 0.01mm over 230 sounds more than good enough – that's 0.0025 degrees.
One 'idea' I have seen is a small block bolted tightly to each of fixed and movable parts of head (as far from pivot as possible obviously) and an 'adjusting' screw to force them slightly apart to true up small errors that appear as you tighten. A bit Heath Robinson but esentially a mechanised method of what I do…