An assembly jig with V blocks for the pins, and mating clamps, plus datum plates and mating clams, would be a good solid way to go bout it, but that is a lot of work for a one-off engine. If making a batch of similar valvegear for other modelers, the jig would be worthwhile. Just food for thought.
Designing and making such jigs for difficult or near impossible assys was a big part of my day job in industry in the early years of my working life. There are a few tricks, one of them being that you can have "leaves" on the jig that slide in and out in gibs (or just with slots on shoulder screws if high precision isn't required) to engage and disengage the assy to get parts in / aligned and then back out again. Start with a smooth flat datum surface on a base plate, and build up from there. Such a plate and attached parts can always be turned vertical or angled after the fact if need be.