Posted by SillyOldDuffer on 13/03/2020 21:54:30:
Pedant Alert!
Unlikely to be the Thermite reaction – there's a simpler alternative. Thermite is a mixture of Iron Oxide and Aluminium Powder. When ignited the Aluminium robs Oxygen from the Iron Oxide leaving molten Iron behind, which can be used to weld steel.
Iron Oxide is unnecessary in this case because air is a much better source of Oxygen.
It's normally difficult to ignite Aluminium because an impermeable Oxide skin forms instantly to snuff out the reaction. It stops air getting to the metal. Finely powdered Aluminium is the exception. Once started, the flame blows nearby unburned powder into the air and ignites it. In the right conditions a pile of Aluminium powder goes off like old-fashioned photographic flash powder. Lots of heat, close to an explosion.
Aluminium is so hard to ignite it's safe to machine it without any special precautions. Not so certain other metals. Magnesium and Titanium have to be treated with extreme caution. Grinding either is likely to cause fireworks. Never pour water on an Magnesium fire – it explodes!
Perhaps the most dangerous material to machine is Plutonium. Ebay don't sell it! Fortunately Model Engineers are unlikely to need to machine any reactive or toxic metals.
Dave
This is not totally correct, but having ignited bulk thermite (not easy, nomal approch is to use magnesium ribbon) I can see were you are coming from. "Thermite" sparks are actually common but not often recognised. They were identified as a cause of ignition in refinery fires when aluminium (or titanium) objects were dropped on rusty steel. Hot steel sparks thrown onto a pile of mixed aluminium and rust can and does cause ignition (not when you want it to).
There are other hazards with light alloys I once set "fire" to a 5" diameter by 8" long piece of unknown composition alloy when tappng some blind holes. I used some spray solvent to clean chips out of the blind hole and noticed smoke coming out. The solvent was trichloreythlene and reacted with the alloy. A handy bucket of water stopped it.
Robert G8RPI.
Edited By Robert Atkinson 2 on 17/03/2020 15:07:39