All metric countersunk screws should be 90 degree.
You might find that the North American screw threads are 82 degrees; although I live where the UNC/UNF reign supreme, I use solely metric, so don't quote me on other threads, like BA and ME!
I generally use a 90 degree countersunk; most of mine are about 6 flute. Take it slowly for metal, the cutting surface is rather large. (don't know about fiberous non-metalic surfaces)
In theory, you should have a countersink that matches the OD of your screw head so that there is a very slight parallel where the widest part of the screw head is, so that the screw head goes flush, but the countersunk hole does not look overly large. I generally just don't bother worring about this part!
Another JohnS.