If the boiler is being re-built from one which has been soft soldered, you may have a serious problem. When heated above its (low) melting point the lead or tin (etc) from the slightest trace of soft solder left in place is liable to soak into the surrounding brass (or copper) giving a very odd alloy which will not take the hard solder.
Secondly, battery acid (dilute sulphuric) is perfectly good to remove hard-solder flux residues. Half an hour should be enough. Use the acid as it comes (new and not out of a battery) or let it down 50/50. And as it is dilute acid, do not panic about adding water to acid or vice versa. But do resist the temptation to plunge the still-hot job into the acid – the splashes will make holes in your jeans, your vest, and anything else around. Was away any splashes with a solution of washing soda (Sodium Carbonate) or baking soda (Sodium bicarbonate).
And do practice hard soldering first, on some off-cuts of the material you are using. Get both sides to the same 'just red in the dark' temperature, and remember that the solder will flow into the hottest part of the joint.
Hope this helps.
Cheers, Tim