"Briggs and Stratton engines use aluminium bores with no coatings but they run a plated piston ( can't remember if it was silver or nickle or tin )to stop any galling ."
I believe Villiers did the same with a lightweight range of small engines. As has been pointed out, Aluminium running on Aluminium does not work well. I'm not too sure about stainless steel and Aluminium, galling is not unknown with that combination.
Whatever combination the OP decides to use then I would suggest the first step in considering the clearance would be to consider the relative thermal expansions and go from there.
John