Posted by Mark Rand on 04/04/2018 11:38:16:
Surely the carbon (dioxide) goes straight back in to the cement over the next 25 or so years as the concrete sets and continues gaining strength?
Afraid not. Raw material is calcium carbonate mainly (around 2/3 of the mix). Cement hydrates to form calcium silicate interwoven crystal structures. Only the fee lime in the cement (not all of the lime in the raw materials is converted to silicates) etc during the ‘burning process’ within the kiln will slowly absorb CO2 and revert to calcium carbonate.
Typical free lime in a cement can vary between less than 1% to about 5%. Some of this free lime may react with other components in the concrete mix – such as fly ash or slag.
There is a difference between setting (a few hours usually) and curing (strength increase).
The early strength increase is derived from the tri-calcium silicate in the cement and later strength is derived from the di-calcium silicates. Both reactions take place (start) at the same time, but the rates of hydration are different.
Hope that changes your ‘oplnion’ on the subject of cement hydration (the clue is in the word ‘hydration&rsquo
. 
Edited By not done it yet on 04/04/2018 13:41:23