Yes you could put a blob mid width of the "spoke" and then tack the edges. It may get a bit too hot for it but will hold long enough to tack.
You want "original formula" in the red and black tubes not the rapid or marine
If its going to be welded then the filler for forming the fillets could be something that is a bit quicker to sand like car body filler, I tend to use the JBW where I need it's strength or heat resistance but UPOL filler for any cosmetics.