Hello Gary,
Any darkish coloured spray paint will give a contrast medium against which scribed lines can be readily seen will do just fine. Matt finish grey primer stops the shine and shows pencil marks as well, helpful in noting hole sizes against location point. However, this part comes later, see next para.
I don't know the castings but with any project involving castings you need a reference face from which other measurements can be taken; it could well be the base on this model. First go over that surface with a coarse file to knock down the lumps and rough surfaces before holding the casting in a 4 jaw chuck to skim it and make a reference face of it. Try to cut under the outer skin to preserve the tool edge without taking off more metal than necessary. As for hollows in the base, they are probably out of site when it is sitting down on a plinth and will have been bridged in the skimming, so they shouldn't be any more than cosmetic.
Now you can paint the other surfaces and mark it all up.
I hope that helps
Regards Brian