Michael, there has to be other holes anyway and a central one used as a reference when I set the part at 45 degrees on the mill table make good sense.
George, I was hoping to use a method that did not involve marking out as that just adds another two chances of variability creeping in (marking in the first place and following the marks in the second)
Jason, I basically use the acute edge as a reference but (whilst this part does not need micron precision) my concern was whether any machining burr would extend the edge and if so whether to remove it. I now think that if I use a new cutter and take a very fine finishing cut on the face there would be no perceptible burr. I have had an edge finder for years but this will be the first time I've used it!
Ian