This piqued my curiosity, so I've just had a furtle in the shed with my set of BOC nozzles. I have a set of the swaged copper nozzles to suit a BOC Sapphire 3 torch, and by dint of poking bits of wire and small drills up the orifice I've come up with the following:
#1 nozzle is 0.6 mm dia, #3 = 0.8 mm, #5 = 1.0 mm
#7 = 1.3 mm, #10 = 1.4 mm, #13 = 1.6 mm
#16 = 1.8 – 1.9mm (1.8 is loose, 1.9 won't go), #25 = 2.0 mm, 35 = 2.4 mm
It's hardly a precision measurement but it'll give a rough guide.
If anyone has got one of the sets of wire reamers BOC sold for nozzle cleaners these would give the sizes more accurately. I've always assumed that the numbering system, though peculiar to BOC, was the same for all their torches, but I haven't checked. Am I right in thinking the numbering system is related to the fuel gas consumption in some way?
As Fizzy says above, for silver soldering something as large and as heat-dissipative as a copper boiler you'll want a bloody big flame and I would think quite possibly a second torch – probably propane – to help with getting the whole thing pretty hot, then go in with the oxy-acetylene to trim the local temp' and get the solder to flow. Getting a structurally sound joint is a matter of getting on with the job, getting a structurally sound and pretty result is another stage of magic again. My Dad was a silversmith, and together we hard soldered some pretty crazy things (the broken antler on a brass statue of a deer was one) but you don't have time to hang around before the flux stops absorbing oxygen and you're knackered. That was with JM EasyFlo flux; I gather there are better fluxes around now, so good luck!
Do let us know how it goes. Rgds Simon