Thanks guys, we've got some aluminium MIG welding wire and some goo specially formulated for bonding ally busbars. We're going to try ally pop rivets and I've made some ally washers for holding the wires on, so we don't have any dissimilar metals. I'll keep you posted, but wait till we've had a winter before getting too cocky!
Don't fancy solder as it's out in the field and we have plastic sleepers, visions of meled plastic everywhere