On larger gears it is quite possible to determine the pressure angle by a series measurements over the flanks of several teeth by means of a vernier or digital caliper then refferring to a table of base pitches. I am not sure if the normal digital caper in the home workshop will get into the tooth spaces of a 32DP gear and give a sufficiently accurate result.
However the procedure is as follows. Select any one of the gears you have and open the caliper to span across the flanks of several teeth (for example for a fifty tooth gear span 5 or 7 teeth). Take the measurement as accurrately as possible and note the dimension, then another measurement over one less number of teeth than the first reading and note this dimension. then subtract the second size from the first and note the result,
For 32DP 14,5 degree PA the measurent should be 0.0950 inches
For 32 DP 20 degree PA the measurement should be 0.0923 inches.
As the difference is only 0.0027 inches it may be necessary to take a few readings to come to a conclusion.
Regards
Ted Brown