Pre-war tyre tubes were made from natural rubber made from tree sap. One process in manufacture was 'vulcanisation' – the rubber was heated with added sulfur, and this stiffened the rubber and avoided stickiness. Patches could be used to mend holes and tears, and were attached using heat and sulfur – hence the smoke and the smell of fireworks.
Post-war rubber holds air better but does not work so well with old-style natural patches – they were replaced by a solvent method.
Cheers, Tim
PS two of those involved in working out the vulcanisation processes were Mackintosh and Goodyear – names that still resonate in the minds of the public.