As I understand it, Alibre have their own forum where questions about use and capability of the software are usefully answered (including the most efficient way to achieve your aim if it is not native to the software level you choose). A simple google search finds a good spring-off point:
e.g. https://www.alibre.com/blog/the-math-behind-involute-spur-gears/
On that forum, almost everyone who posts would be a user of the software. You thus have a far greater chance of a canonical answer than here, where only a sub-set of the membership will use Atom3D and a sub-set of that sub-set use the software for drawing gears.
In a similar manner, their sales people would be able to tell you if the gear-creation capability is included in the software product level you are considering purchasing.
For 3D printing specifically, the ability to apply a generous fillet to the root of the gear, to beef up its bending capacity and reduce stress concentration, is a consideration. Gears made for additive manufacturing do not need to be made the same shape as ones for subtractive manufacturing as no cutter is involved in producing the tooth space.