I have four of these, bought at a batch for very little money a couple of years ago.
Mine are well worn, with comparatively deep grooves in the V faces; three seem to be near enough right angled, but one, like yours, is a degree or so off.
I was considering re-grinding the V faces on a small Herbert Junior, but have been putting the job off until I can come up with a way to ensure the two refurbished faces will have exactly the same amount taken off, whilst still retaining the 90° angle, and being equidistantly aligned to the axis of rotation of the micrometer head.
Unlike more sophisticated grinders, the Herbert only has a micrometer adjustment on the vertical axis, so front to back needs a dial gauge and careful handle twiddling, with no feed lock.
Bill