Good afternoon Pete,
As Luigi has said, soft pop valves are the way forward and if you are operating the locomotive at 100 psi then a 10% is the maximum permissible rise allowable. Both valves must be set to the same release pressure, there's no advantage in setting one valve higher than the other, you may as well leave it in your tool box! Please remember, these are the most important components on your locomotive and should also be carefully maintained.
It is useful to have a reasonably sized pressure gauge, 3" diameter or so, to say 200 -250 psi either certified or checked against your local clubs master for setting the valves when the locomotive is in steam, also it is a requirement to have a red line on the face of the dial (not as I've seen sometimes, on the glass) indicating the maximum permissible working pressure.
On a recent overhaul of a 5" gauge locomotive I took the safety valves apart to check the components and to my surprise one valve was partially scaled over, no doubt due to lack of use.
Polly Engineering can supply both a drawing and suitable springs should you wish to make up your own soft pop valves (usual disclaimer, only a satisfied user)
Please see below the partially blocked safety valve: –

Regards,
Bob Youldon