Let me guess – the part to be bent is shown held in a collet-holder, and the bend needs to start as close as possible to the radius where the long smaller-diameter section starts to increase in diameter? And the part is solid and made of mild steel?
If so, I suggest that you abandon the collet idea (it is likely to get too hot), and find two steel tubes, one large, one small, to fit over each end of the part. The fit needs to be loose enough to fit easily over the small end even when it has expanded with heat (say 1-2mm clearance); the tube for the larger end can be a light push fit, or if looser than that, make a slot along it so the vice will close it onto the part to hold it firmly in the vice. The larger diameter tube will be held in the vice horizontally (so the full length of the tube is held firmly with the part inside it). Then heat the length to be bent with a fairly large flame (a big propane job or oxy-acetylene), and when the relevant length is nicely red-hot, slip the short tube over the end of the part which is sticking out, and pull it towards you keeping the newly-bent section horizontal (or it might slip round in the vice).
Depending on how accurate your 45 degrees needs to be, it would help, before you start heating, to mark a template (eg cardboard) with the required angle as a guide to the pulling operation. To get the angle exact, if your first go is not good enough, it would be best to wait until the whole set-up has cooled (eg overnight) before you heat the bent section again, otherwise the whole thing is going to get much too hot – vice as well. It might be possible to tweak the angle a degree or two when cold, using the same tooling, if you handle-tube is long enough, the vice is firmly bolted to the bench, and the bench to the wall. The more you can concentrate the heat on a short length, the tighter the radius will be, and the harder you will need to pull.
The heat will of course cause the heated surfaces to blacken in the really hot bits, with various colours working outwards. These surface effects can be removed back to bright steel with time and emery cloth, or using a soft abrasive wheel in a polishing rig.
If the steel is not a mild steel, it is likely to be harder to bend, and the heat treatment is likely to modify its properties – especially hardness. How much this matters depends on the use of the finished article. In this case do not risk cooling any part of the job more quickly by spraying with water (etc) as this is likely to cause odd heat-treatment effects. With a mild-steel part, cooling in water should not have any effect – that's why it is called 'mild'.
I hope this helps …
PS just read the title again – the olny place it says 'stainless' but which spec of stainless, I wonder?
Tim
Edited By Tim Stevens on 19/10/2019 17:18:00
Edited By Tim Stevens on 19/10/2019 17:19:21