I would have a good look at the contents of that water-butt! Last month I replaced one and although the water at the tap looked OK the inside of the old butt was unpleasant. Much more like drowned snail soup than Evian.
Rainwater is acidic due to Carbon Dioxide and pollution. Just how acidic your rainwater is depends on where you live and how polluted your air happens to be when it rains.
My water-butt is fed from a tiled garage roof. There is plenty of opportunity for minerals and other nastiness such as bird poo to be dissolved by the acidic water as it drains into the butt. Once inside the mixture can go to work on the snails. Given enough time the result will be hard water because snail shells are made of Calcium Carbonate. And there will be lots of microscopic rotting vegetable matter and bacteria in the water as well.
Rainwater is a good idea for boilers but you have to be careful to keep it clean during collection and storage. I doubt that a filter on an ordinary water-butt is good enough, especially if the water has had time to develop an eco-system!