I had worked as a tv engineer for many years and dealt with changing the old black & white and CRT colour tubes, one thing you may not be aware of is that the high voltage used for colour tubes around 25kV charges up the glass dielectric just like a capacitor, and the charged glass slowly releases its charge over quite a long period of time into the 'plates' producing a very high voltage.
The same goes for the black & white tubes but with only about 16kV.
So…when handling the tube, don't put your finger in the little connector hole!!! even if it was months ago that the tv set was used and even if you short the thing out with a couple of screwdrivers from the hole connector to the outer coating of the tube..! it can re-charge itself and give you a nasty reminder that the electric stresses in the glass are still there.
I don't advise smashing the tubes and there is not much inside to use, the colour tubes do have a 'shadow mask' which is like a very fine sieve …. please also be aware that on being smashed a kind of dust seems to be emitted which may be the phosphor from the screen.
..Bob..