Hello Paul,
Chuck jaws are made in matched sets to suit the chuck they are supplied with. Those look like an inside and outside set for a three jaw self centreing chuck, but they may not even be of Pratt manufacture. The only exception would be for soft jaws without the outer steps, but they will still have to match the scroll pitch and at 1/3 a revolution difference across the set to grip work correctly. Being stepped these are not soft jaws.
If the slot is too narrow there is no way they will even enter you five inch chuck and being shorter too I suspect they originally belonged to a four inch or even three inch chuck.
Sadly I don't think you can use them but rather than bin them offer them on ebay [ suit 3 J chuck, make and size not known] and see what they fetch. You might be surprised
Brian.