I wouldn't use black ms on account of the difficulty of cleaning off the scale prior to painting.
EN 32B is described as case hardening material, which I'd not expect to use for frames.
I've used the sheared plate ms, as supplied by Reeves etc etc.with no problems. I think its in an annealed condition after rolling, maybe CR4. Get it over the required width and cut material from both long edges to bring it to width, otherwise the stresses in the sheared edges could cause distortion.