I have a Wimshurst machine. It was originally built by my father, and restored by both of us during the 60's. It is now in need of a bit more restoration, which I hope to find time for soon. As to the principal that it works on… The main thing is charge separation, eg if you have a charged capacitor and you pull the plates apart, the Voltage will increase. This is reasonable enough, since you have reduced the capacitance so for the stored energy to remain the same the Voltage must go up. All very well, but where does the initial charge come from? Anyway, they work fine and are fun to play with, especially in a darkened room. They tend not to work so well in damp conditions. I think this one was originally described in ME, although it would be before the forties, which is where my own collection starts. When you start turning the handle, you can feel the load come on when the machine begins to charge.
Different materials tend to give different polarities when rubbed, and I would agree that probably the dye is making the difference.
Did you know that pulling sellotape off the roll generates low energy X-rays? If you do that in the dark you can see sparks too.
The Faraday Centre in Napier (a technology museum) has a Tesla coil…now that makes some serious sparks.
John