Knowing a bit about building bikes, if the spokes go from the hub to the smaller rim, then from the smaller rim to the bigger one, you will almost certainly never get that to run true.
Building a strong and true wheel is all about triangulation of the spokes to hub, and a rear wheel is offset to allow for the cassette, I would say it would be almost impossible to get it to work, and you would spend a lot of time achieving something that won't work.
Wheel building is an art, that isn't easy to achieve, and I certainly wouldn't start this way.
Edited By David Standing 1 on 11/05/2018 17:02:38