Thought about plastic sections as i have plenty of prior experience using plastic in scratch-building model railway stuff, but don't think it would be robust enough to survive long, hence original thought of using Code 100 rail with the flat-bottom being the outside, the rail head the inside, and the acrylic sheet sitting within the recess between rail head and base.
Did not consider 3D, there are few places in this part of the world offering this service in metals, but a friend has recently had some small brackets made in brass by this method so i'll check it out.
Thanks all for the feedback.