I did a search for stepped Vee pulleys, and was surprised at how many people make them. It was just in the application information section of their web sites.
There seem to be fairly strict limits on minimum pulley diameters, maximum ratios and shaft centre distances.
I needed a four step pulley to get the speed range on a mill, and to get a nice geometric ratio of speeds needed 3, 4, 5 and 6 inches at least, but 4" would be better to get the thing to actually drive when in the step up direction.
Use poly-vee belts? Expensive though.