Why silver solder? Please bear with me !
There are several types of brazing alloy.
nickel brazing alloys – marine
gold brazing alloys – jet engines
palladium brazing alloys – jet engines
copper brazing alloys (includes brass and copper-phosphorus alloys eg silfos)
silver brazing alloys (silver solders)
Brazing defines the metal joining process not the alloy
Copper alloys are the cheapest and very versatile. So there has to be a very good reason to move away from them . That is invariably due to a technical reason. These include melting temperature, parent material combination, corrosion resistance, even colour or a combination.
The success of the process depends on correct joint design, heating technique and fluxing. If these criteria are not met no brazing alloy will work.
Peter, a word of caution. Silfos contains phosphorus. It appears to work well but combines with iron (in all steels) and nickel to create a very brittle intermetallic compound that can lead to catastrophic joint failure when stressed.
Copper phosphorus brazing alloys used to join copper nickel pipes on a submarine is thought to be the reason a submarine did not return from its' test dive.
keith