I think, from my research, you're raising one of the most controversial topics in m.e. !
Likewise having GM cylinder castings (1.5" D) I began looking for suitable metal rings – far too expensive to buy ready-made (e.g. in stainless or PB).
Ordinary O rings were regularly reported to be intrinsically unsuitable for piston rings – according to many experts online & in mags.
So then I purchased the expensive Fluorosint (PTFE+mica) and made rings with scarf joints. More dire warnings surfaced about its considerable expansion at steam temps and consequential need to reduce their diameter at room temp to allow for this.
But of course it was then impossible to run the engine on air…….bugger.
Next, I saw an article on David Carpenter's website about the use of PEEK for rings. "Much preferable to PTFE blah, blah…." The article contained compicated equations for allowing an overlapping joint to close up at steam temps whilst still allowing running on air. Eventually I contacted the author who explained the maths and acknowledged some errors. But ~ the job required several jigs to be made. I decided to buy PEEK-CA30*.
I made the jigs, rings and fitted them. (Finding old articles on http://modelengineeringwebsite.com is difficult so if you're interested, I can provide a copy as well as some of the many pitfalls not covered by the author).
Satisfied after all this effort, I put steam at 40 psi into the GM cylinders only to find they were extremely porous castings and were fit only for scrap……….bugger again, even more so.
Now in the process of maching cast iron cylinders & will joyfully use CI rings.
I appreciate there are innumerable reports of successful use of O rings over many years and PTFE rings similarly. But searching the properties of PTFE and various additives (graphite, mica, glass fibre etc) makes the cautious-minded hesitate if the prospect of running on air is a literal & metaphorical non-starter.
*
PEEK CA30 has a linear thermal expansion coefficient of half that of Fluorosint Mica and a melt point of 340⁰C. In addition the manufacturers state:-
“PEEK CA30 offers higher stiffness and strength than both PEEK and PEEK HPV. In addition it has superior long term creep properties at elevated temperatures of up to 250°C. These features make PEEK CA30 ideal for applications involving high static loads.
• Wide operating range (-20°C to +250°C)
• Excellent hydrolysis resistance
• Excellent mechanical strength / stiffness
• Outstanding dimensional stability
• Exceptional wear resistance”