Assuming that the chamfer is 45 degrees and the corner of the block is 90 degrees, you only need the chamfer distance to calculate this:
In either a side or end view of the part (does not matter because the chamfer is 45 and the corner is 90), you see the vertical height of the chamfer (top to bottom) as a true length (1). This is the chamfer distance.
In a plan view of the chamfer, you see the base length as a true length. It is the hypoteneuse of a 45 degree right triangle with side length = chamfer distance (2) .
Those two lengths allow you to calculate the true length of the intersection slope (the vertex of your unfolded pattern) (3).
The side or end view gives you the true length of the chamfer (the sloping bit) (4).
(3) and (4) allow you to calculate the half angle.
Using the same reasoning, you can write a general formula where the inputs are: chamfer angle, a characteristic chamfer distance (either vertical or horizontal) and corner angle.
A good place to start is an old technical drawing book, where you learn how to draw a view of something such that a particular feature is shown as its true length and its angle to a plane is a true angle.