it is very simple.
on a miniature steam loco with copper silver soldered boiler all bushes silver soldered to the boiler should be made of bronze or copper. copper was an LBSC thing that isnt followed nowadays for bushes. for bronze avoid gunmetal as can be porous and isnt as tough for threading as good old fashioned hard drawn phos bronze, and avoid phos bronze with lead added.
brass is a NO for boiler bushes firstly because in the course of silver soldering up the boiler the brass can get over heated, plus as stated, is subject to dezincification. now if the fittings are brass and suffer dezincification they can be replaced. if the boiler bushes deteriorate then that usually results in a scrapped boiler.
whether you make boiler fittings out of brass or bronze is entirely up to the builder, and most commercial fittings are all brass. however boiler bushes silver soldered to the boiler are quite another matter as explained above.
i still have brass boiler fittings on many of my locos. they get checked regularly. no dezincification. some of these fittings are 30 years old. i have injectors the same age with no dezincification on the brass cones. i even have a Linden injector over 60 years old with no dezincification on the brass cones.
however ive replaced all the brass fittings on boilers of club locos where dezincification has occured, but probably not until after 20 years or so use and probably the boiler not being blown dowbn after each run/steam up.
cheers,
julian