If the lead content exceeds 2%, it can affect the brazing operation.
It can form an unwettable dross at the interface.
It can cause cracking.
These effects can be reduced by adequate fluxing and uniform heating without imposed stress.
Source of information – BS EN 14324:2004 Section 5.1.2.8
This document would be of great interest to the model engineer. It defines the process. Silver soldering is part of the brazing process. Silver solders, conforming to BS EN 1044, as used by model engineers, are referred to as silver brazing alloys. Brazed joints can be made with copper, silver, nickel, gold, palladium and aluminium alloys.
It offers guidance on joint design and heating techniques.
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If the model engineer reads and understands this document, he will produce stronger, neater, cheaper joints. Brazing is a simple process, made difficult by not sticking to the basic principles. It is a skillful process, but this document will highlight where to develop your skills. Then, it's practice, practice.
Keith