Yep. Duncan has it.
Too much to hope that the BBC is actually aware of things like phase diagrams. Let alone what they mean.
You need cooling to liquify atmospheric gases (except carbon dioxide). Commonly called regenerative systems. Incoming gas at high pressure goes through a heat echanger and thence to a nozzle pointing at said heat exchanger. The expansion of the gas it rushes out of the nozzle cools it which in turn cools the heat exchanger so the gas passing through it is also cooled. After a while the heat exchanger is cold enough that liquid nitrogen comes out of the nozzle as well as cold gas.
Well thats the theory.
As anyone who has used small Joule-Thompson coolers to produce liquid nitrogen from high pressure nitrogen gas seriously frustrating) or high pressure air (seriously, seriously frustrating as in jumping up and down tearing your hair out screaming profanities) the real world is less than co-operative. Given half a chance the systems will ice up, stopping flow and basically sit there sticking its tongue out at you saying Nah, Nah, Nah until its warmed up enough to evaporate everything. Which takes a while and, given that you are trying to cool things down, warming up is counterproductive.
In practice its likely that only nitrogen will be used. The other gases being filtered out. Oxygen condenses a little before nitrogen so a mix could be used but care is needed to avoid cold spots where oxygen ice could form and block flow. Annoying with a small JT cooler, potentially lethal in an industrial scale system.
The efficiency figures are suspiciously high. Link implies an isothermal system efficiency of 60 to 70% which seems unlikely.
Need to start with around 3,500 psi to regeneratively liquify nitrogen. Compressing air is notoriously inefficient, be doing well to get 80% compressor efficiency. Lots of waste head to deal with as well as the noise from a big reciprocating compressor. Screw types can't deliver the pressures needed. So that's over half the quoted loss budget gone already.
Expansion ratio of nitrogen when it goes from liquid to gas is just under 700, under half that of water which is 1600 when going to wet steam. So output turbine performance may be compromised. Especially as there is no equivalent to superheating or other tricks to get more energy in. The output side is going to get very cold too. The energy to evaporate the liquid will come from the ambient surroundings. For all practical purposes the sytem analyses as a heat pump. All the output energy is drawn from the surroundings.
Frankly I'd be surprised if the calculated output stage isothermal efficiency were much over 60%.
Looks something of a fraud to me.
Clive
Edited By Clive Foster on 08/11/2020 18:24:17
Edited By Clive Foster on 08/11/2020 18:24:47