Hi Robin,
Can't help but wonder what your supplier suggested?
Your item is not going to be hallmarked so why use a hallmarking grade of silver solder?
Why not use a more readily available alloy with 55% silver as opposed to the 67% and with a lower melting point and cheaper?
When I worked as a Technical Sales Rep for Johnson Matthey Metals we made bi-metal sheet and strip by hot rolling fine silver 99.95% into a groove cut into the brass. The resultant slab was then rolled to the finished required thickness.
So your hot working technique could work.
Fine silver will work harden, but it will anneal at relatively low temperature. Keep it on a domestic radiator long enough will anneal it!
Do Cookson sell fine silver wire?
Got any silver fuse wire?
Know any electroplaters that might cut you a sliver from an anode?
Will your local MANUFACTURING jewellery company or bullion dealer provide you with a lead? Forget the high street.
You could always ask Johnson Matthey!
If you opt to go down the brazing route consider using a paste containing flux and filler metal in the bottom of the groove. Lay the circle on the top. Heat as suggested by Bill, from underneath.
Declaration of interest – like the information you can get the paste from CuP Alloys!