When I made my 6 wheel tender with flared top I used a steel bar with the desired radius welded to a flat plate of steel as the former. To do this you'd sit the bar and the plate on a flat surface and weld them such that the plate was sort of tangential to the bar.
The brass was sat upon this, situated so the start of the bend was where the bar joined the plate.
Another flat sheet laid on top of the brass, and everything clamp together. A bit like Julian's solution.
I did anneal the brass. I think I did that when it was already clamped between the two sheets of steel.
Then just tap the brass over the former. Luckily it worked well – I would have been upset after drilling all the rivet holes if I messed up!
The join at the rear corners was tricky, I just kept filing until I had a reasonable fit. I did mess up the rear plate of the tender and had to make another.
Sorry I don't have a photo of it, I borrowed the steel bits off a club member.