There is no reason why a propane fired boiler cannot be put together using copper phosphorus alloys (CuP Alloys) that may or may not contain silver.
Gas fired water heaters, central heating boilers are all made using these alloys.
BUT
DO NOT USE THEM ON COAL FIRED APPLICATIONS.
a hot sulphur bearing atmosphere can cut through a copper phosphorus joint like a hot knife through butter!
regards
Keith