I don’t use aluminium that often, most of the things I make are made from BMS. That said, I think that the most useful sizes will translate across various different materials. It’s very common to see metric equivalents of Imperial sizes in engineering. Probably because old plans and diagrams have been converted.
For me.
10, 12, 16, 20 & 25mm (3/8, 1/2, 5/8, 3/4 & 1 inch.) Rounds
3, 6, 10 & 12mm (1/8, 1/4, 3/8 & 1/2 inch) Flats
12, 16, 20, & 25mm (1/2, 5/8, 3/4 & 1 inch) Square