Be wary of using a gear or bearing puller on the sprocket. It would be too easy to bend the teeth and ruin it!
You don't need to warned of the difficulty of finding a replacement.
A Woodruff key will only locate the sprocket in angular terms relative to the shaft, it is not a retaining device.
You need to decide how the disc at the front retains the sprocket. Look VERY carefully at the boundary between the disc and the shaft to see if there is a thread.
Then you have to try to work out whether the thread is right or left hand. Once you decide on that the problem is how to hold the disc to rotate it relative to the shaft.
As suggested using a chain around the sprocket can be used either to hold the sprocket stationary while the disc is slackened , or to rotate the sprocket and shaft around the disc while it is held by a strap wrench, or in the jaws of a vice.t
Once it apart, you may decide to depart from prototype, by making a pin spanner and drilling two holes in the disc to match the pin spanner.
Howard