On flat surfaces, a soft joint will always eventually lead to torque relaxation of the fixings, (Due to joint settlement ) which may result in leakage.
A sealant on a soft joint can also act as a lubricant, allowing the joint to be extruded in the vicinity of the fixings!
If you are confident of the flatness of the faces, a metal to metal joint, with a sealant to fill any gaps, such as machining marks, will remove the risk of settlement. Suitable sealants could include Hylomar (As already said, difficult to remove any excess without solvent such as Methyl Chloride, or scraping ) Silicon Rubber, but paint will not adhere to it, so again, scrape off any excess.
A non setting sealant will make any subsequent dis assembly easier.
It can be very difficult to break a joint sealed with a hard setting sealants such as Hermetite. So difficult that parts are damaged before they separate.
The old builders of Cornish Beam Engines, admittedly working at not much more than 40 psi, used metal to metal joints with things like putty or lead strip as gap fillers, between cylinders and their covers..
Howard