Hello from Rural Wales
I have made a Simms coupling not too long ago, so perhaps I can help.
Look closely at the bronze coupling in an earlier post, and I think you will see that the spaces between the teeth are (as near as a casting can be) semicircles, and the same section of semicircles from inside to outside. This is very helpful, as it means you can cut the hollows using a simple end mill or slot cutter. My guess is that this is how Simms made them in the first place, and the picture shows a later copy. So, forget about searching for fancy cutters, as they won't be correct anyway.
I don't know what kit you have apart from your dividing head, but I think I started by making a dummy spindle with the correct taper and keyway, so you can rotate the coupling precisely in the jaws of the dividing head chuck. You do need to get the taper in the new part bang on, to fit your dummy and the original spindle, as otherwise it will fidget, come loose, and wear the shaft before you notice anything wrong. It would be worth considering a lump of engineering aluminium alloy, if bronze is difficult to find locally. And I hope you have the necessary dividing plate with 19 holes (or 38) – but if not you might need to make one to be sure the angles are all the same.
If you need dimensions for the finished coupling (or half-coupling, to be precise) then come back to me and I will grope about in my freezing garage once it has stopped snowing.
Regards – Tim Stevens