Assuming we are talking about anything bigger than a Mamod boiler…
Forget all that analytical stuff. The MELG Guide Book (latest has a white cover with orange titles) tells you what you actually need to know.
It mentions certificates only for steel boilers, but places so many obstacles in their way that making a steel boiler is for the professional only, for all practical purposes.
(Curiously the original EU Pressure Equipment Regulations that our hobby sort of uses, mentions only two materials for pressure-vessels: aluminium-alloy and stainless-steel; but not which of a plethora of their alloys and grades!)
Copper and cuprous alloys, and silver-solders and fluxes – purchase by what it says on the drawings, and if you buy them from reputable suppliers they are what they say they are on the invoice. You don't need certificates of conformity for them, for amateur construction not by way of trade, and nor should your club's boiler-testers demand them, though they might want to inspect progress.
Just don't use brass in any structural component including the bushes for clacks etc. Rather according to alloy, it can become brittle in some circumstances and conditions.
The question mentions stainless-steel. I am afraid that is irrelevant. I think it's still ruled out, but anyway it comes in so many flavours with their own welding characteristics, that whilst there is no logical reason against stainless-steel boiler shells in principle, it is definitely a material for the professional boiler-makers able to choose the right alloy and weld it correctly.