I'd seriously rethink the necessity for the radius of the end of the slot to match the diameter of the bar so exactly. With two flats machined on it, captive in the slot, hard up against the end of the slot, it's not going to go anywhere.
With no idea given of what the bar and slot are to be used for, working conditions, stress loads, etc etc, it's hard to imagine why the slot's end radius would be so critical.
Whichever way you go about it, the said task is tricky. Rotary table will leave a radius at the join that needs filing out. So you might be best to file the radius entirely to shape. Make two "reverse" filing buttons by turning a washer out of silver steel with a hole in the middle of the desired radius. Cut them in half, leaving one half a full exact half, and harden them. Clamp them in position, or screw them in place if possible, and file the slot to match the buttons.
Lot of mucking about if you don't really need that close a match.