David,
Mmmm, well……… Like I said I don't have any intimate knowledge of the DNY apart from having seen a few! Never looked at the drawings or made any bits for one! Just thinking it through from general principles though, a few questions;
You said in the first post you could hear air coming from the exhaust. Is this a full volume flow of what you are feeding in or just a wisp?
Did you confirm as Jason suggested that the slide valve (I assume it is a slide and not a piston valve) is free to float on the valve spindle and can find its own seat on the valve face?
Depending on answers depends on where to look next.
Some suggestions though;
Is there a tapping anywhere direct into the valve chest, lubricator input perhaps, where you could put live air direct into the valve chest.and bypass everything between boiler and valve chest?
Are you sure you have the timing right?
Are you sure you have done all the required drillings (silly question perhaps but sometimes it's easy to overlook something).
Paul.