Is brass best?
The answer to the original post is 'no' but it will work – probably just as well as some other alternatives. As soon as gibs allow any lateral movement, there will be a considerable force applied by the machine across the slideway. That may accelerate the wear on the gib/slideway. Think here white metal bearings for crank pins. Lead/tin white metal is suitable for petrol engines, but diesels require something a little harder – more tin, some antimony and, latterly, indium as well.
Perhaps the gib might wear rather than the slideways initially, I don't know, but likely a steel gib would give better/longer service life overall. Microscopes don't have any lateral loading, so not really comparable, I would think. As far as I know bearings were brass, unless bronze was substituted for a good reason. Slow moving, large area, well greased and easily/cheaply replaced. I know that bronze was used, in preference to brass, in disc coulters on ploughs, probably due to the side loading, but perhaps because of the harsher environment.
But get the right type of brass, as there are several and some are better than others for different applications.