Not only starting.
The 90º crank-setting was normal for twin-cylinder steam-engines, to aid starting in use albeit making balancing in manufacture, more difficult.
Its other reason was to give more even torque per revolution.
The maximum torque from one cylinder comes around mid-stroke, during the minimum, dead-centre, point for the other.
Since the engine is both double-cylinder and double-acting the resultant torque approaches some constancy through the full 360º: a polar plot of effort against angle looks a bit like a four-leafed clover. The flywheel inertia smooths the curve to some extent, making such engines very good for driving directly-coupled dynamos and similar duties.