None of the basic parameters such as pitch circle diameter, circular pitch and tooth depth are affected by the pressure angle. So there is no need to do any calculations when changing between 20PA and 14.5PA. A pressure angle of 14.5PA is more prototypical, although I’ve chosen 20PA for all my traction engine gears.
As Jason says changing to an integer Mod value will be a nightmare. You’ll end up redesigning half the engine.
I’d be slightly cautious about cheap cutter sets. I bought some cheap cutters when I was playing with helical gears, but I wouldn’t want to use them for proper gears due to eccentricity and wobble issues, in some cases.
Cutting gears is very satisfying:

Andrew